An unexpected and useful E-ring oxidative cleavage in furostanes
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چکیده
منابع مشابه
Oxidative Ring-Cleavage of Catechol in meta-Position by Superoxide
Superoxide reacts with catechol in dimethylsulfoxide to form a yellow product. The structure of this product was established by different methods. UV-spectra of the yellow compound corre sponded under all circumstances to those of enzymatically produced 2-hydroxymuconic acid semialdehyde. In the presence of ammonia the product was converted to picolinic acid. The UV spectra, the retention time...
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ژورنال
عنوان ژورنال: Arkivoc
سال: 2008
ISSN: 1551-7012
DOI: 10.3998/ark.5550190.0009.e25